Oxidation of some alkoxy-cycloheptatriene derivatives: unusual formation of furan and furanoids from cycloheptatrienes

COSKUN, Ahmet; GUNEY, Murat; Dastan, Arif; BALCI, Metin

doi:10.1016/j.tet.2007.03.145

Oxidation of some alkoxy-cycloheptatriene derivatives: unusual formation of furan and furanoids from cycloheptatrienes

Atıf İçin Kopyala

COSKUN A., GUNEY M., Dastan A., BALCI M.

TETRAHEDRON, cilt.63, sa.23, ss.4944-4950, 2007 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 63 Sayı: 23
Basım Tarihi: 2007
Doi Numarası: 10.1016/j.tet.2007.03.145
Dergi Adı: TETRAHEDRON
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.4944-4950
Atatürk Üniversitesi Adresli: Evet

Özet

The oxidation of some alkoxy tropone and tropone ketal derivatives with singlet oxygen and m-chloroperbenzoic acid was investigated. In most cases furan and furanoid derivatives were isolated. The structures of the formed products were determined by means of spectral data and the formation mechanism of these unusual products is discussed. (c) 2007 Elsevier Ltd. All rights reserved.