Leaching kinetics of magnesite in citric acid solutions

Demir F., Donmez B., Colak S.

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, cilt.36, sa.6, ss.683-688, 2003 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 36 Sayı: 6
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1252/jcej.36.683
  • Dergi Adı: JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.683-688
  • Anahtar Kelimeler: magnesite dissolution, citric acid, leaching kinetics, DISSOLUTION KINETICS, CARBONATE
  • Atatürk Üniversitesi Adresli: Evet

Özet

The solubility of magnesite ore in citric acid, an environmentally friend and natural reagent, was investigated. The effects of reaction temperature, particle size and acid concentration were examined. The leaching rate increased with decreasing particle size and with increasing temperature. The dissolution in terms of acid concentration increased initially and then fell with increasing concentration. By testing shrinking core models for fluid-solid systems, it was observed that the dissolution of magnesite was controlled by chemical reaction. The following semi-empirical model was developed: 1 - (1 - x)(1/3) = 6.4 x 10(7)(D)(-0.17)(C)(0.11)e(-61.35/RT)t, where D is the particle size, C the acid concentration, T the reaction temperature and t the reaction time. The activation energy of the process was 61.35 kJ.mol(-1).