Akademik Veri Yönetim Sistemi
CHEMPHOTOCHEM, cilt.8, sa.9, 2024 (SCI-Expanded)
Molecular organic photocatalysts developed for use in chemical transformation reactions have gained momentum in recent years. In this study, six new triplet photosensitizers were prepared to determine their photocatalyst capabilities and chemical transformation abilities. The chemical structures of the synthesized orthogonal BODIPYs and their cyclotriphosphazene derivatives were analyzed and then their photophysical characteristics including the UV-Vis absorption spectra, fluorescence emission spectra, fluorescence quantum yields, were investigated. The quantitative singlet oxygen formation was determined by chemical trapping using DPBF (diphenylisobenzofuran). In particular, cyclotriphosphazene derivative 12 having three BODIPY moieties showed efficient singlet oxygen production with high photostability and good molar extinction coefficient. The photo-oxidation ratio constant of 1,5-dihydroxynaphthalene (DHN) was calculated as 28.7x10-3 min-1 for compound 12 and at the end of 22.5 min., DHN converted to juglone with 100 % efficiency. In addition, the ability of the compounds to convert 1,3-cyclohexadiene into peroxides in the presence of molecular oxygen and light was investigated and the conversion efficiency was determined by NMR technique. All compounds have been presented as photocatalysts for use in different synthetic photochemistry applications. The first examples of orthogonal BODIPY decorated cyclotriphosphazene derivatives have been prepared. All compounds have high photostability and acceptable singlet oxygen production efficiency. Cyclotriphosphazene-based photocatalysts exhibit high catalytic efficiency in Diels-Alder reactions under visible light, which is promising for different synthetic photochemistry applications. image