A new and efficient synthesis of indenone

ZENGIN M., Dastan A., BALCI M.

SYNTHETIC COMMUNICATIONS, cilt.31, sa.13, ss.1993-1999, 2001 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 31 Sayı: 13
  • Basım Tarihi: 2001
  • Doi Numarası: 10.1081/scc-100104416
  • Dergi Adı: SYNTHETIC COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1993-1999
  • Atatürk Üniversitesi Adresli: Evet

Özet

Reaction of dichloroketone 2 with NEt3 gave indenone (4) in high yield. Catodic reaction of 2 in the presence of C/Pt electrodes afforded the rearranged product 3 in high yield besides a small amount of chlorohydroxyketone 5. Reaction of rearranged dichloroketone 3 with NEt3 provided indenone (4) as the sole product. The mechanism of these reaction was discussed.