One-pot and stereospecific synthesis of cis-1,2-diazides via mitsunobu reaction of epoxides

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Goksu S., Secen H., SUTBEYAZ Y.

SYNTHESIS-STUTTGART, sa.16, ss.2373-2378, 2002 (SCI-Expanded, Scopus)

• Yayın Türü: Makale / Tam Makale
• Basım Tarihi: 2002
• Doi Numarası: 10.1055/s-2002-35264
• Dergi Adı: SYNTHESIS-STUTTGART
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.2373-2378
• Anahtar Kelimeler: Mitsunobu reaction, cis-1,2-diazides, trans-1,2-diazides, epoxides, trans-1,2-diols
• Atatürk Üniversitesi Adresli: Evet

Özet

Mitsunobu reaction of epoxides using hydrazoic acid, diethylazodicarboxylate, and triphenylphosphine as reagents gave the corresponding cis-1,2-diazides in moderate yield. Application of similar reaction conditions to trans-diols furnished the corresponding trans-1,2-diazides.