One-pot and stereospecific synthesis of cis-1,2-diazides via mitsunobu reaction of epoxides
SYNTHESIS-STUTTGART, sa.16, ss.2373-2378, 2002 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Basım Tarihi: 2002
- Doi Numarası: 10.1055/s-2002-35264
- Dergi Adı: SYNTHESIS-STUTTGART
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.2373-2378
- Anahtar Kelimeler: Mitsunobu reaction, cis-1,2-diazides, trans-1,2-diazides, epoxides, trans-1,2-diols
- Atatürk Üniversitesi Adresli: Evet
Özet
Mitsunobu reaction of epoxides using hydrazoic acid, diethylazodicarboxylate, and triphenylphosphine as reagents gave the corresponding cis-1,2-diazides in moderate yield. Application of similar reaction conditions to trans-diols furnished the corresponding trans-1,2-diazides.