Improved perovskite film quality and solar cell performances using dual single solution coating


Baltakesmez A., Biber M., TÜZEMEN S.

JOURNAL OF APPLIED PHYSICS, cilt.122, sa.8, 2017 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 122 Sayı: 8
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1063/1.4985826
  • Dergi Adı: JOURNAL OF APPLIED PHYSICS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Atatürk Üniversitesi Adresli: Evet

Özet

In this study, we present high quality perovskite CH3NH3PbI3-xClx thin films prepared by a combination of static and dynamic coating approaches, named dual single solution coating. Static coating, dynamic coating and the combination of these are comparatively studied. Scanning electron microscopy, X-ray diffraction, atomic force microscopy, UV-visible spectroscopy, and photoluminescence techniques are used for the determination of morphological, structural, and optical properties of thin films prepared using different coating approaches and deposition temperatures. All the coating approaches are repeated at room temperature and with hot deposition. The high quality and density CH3NH3PbI3-xClx films with full surface coverage are obtained using thedual single solution coating, particularly with hot-deposition. The perovskite solar cells prepared by the dual coating approach with hot deposition have better values for all the performance parameters in comparison to the other coating approaches, resulting in high efficiencies. The best device has a short circuit current of 22.03 mA/cm(2), an open circuit voltage of 0.91V, a fill factor of 0.73, and a power conversion efficiency of 14.68% from short-circuit to forward bias, and 22.39 mA/cm(2), 0.91 V, 75% and 15.32% for the vice-versa, respectively. Published by AIP Publishing.