An intramolecular substitution of hydroperoxy-endoperoxide to a bis-endoperoxide
ORGANIC LETTERS, cilt.8, sa.9, ss.1791-1793, 2006 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 8 Sayı: 9
- Basım Tarihi: 2006
- Doi Numarası: 10.1021/ol060272s
- Dergi Adı: ORGANIC LETTERS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.1791-1793
- Atatürk Üniversitesi Adresli: Evet
Özet
A new and stereospecitic synthesis for bis-endoperoxide has been developed starting from tetrahydronaphthalene. Photooxygenation of tetrahydronaphthalene resulted in the formation of hydroperoxy-endoperoxide. The bromination reaction of hydroperoxy-endoperoxide gave bis-endoperoxide, whose exact configuration has been determined by X-ray analysis. The lowest-energy conformer of bis-endoperoxide is the boat-chair form.