Synthesis, Crystal Structure and Thermal Properties of Lead(II) Complex with Bathophenanthroline and Benzoyltrifluoroacetonate Ligands

Hosseini S., Marandi F., ŞAHİN E., Musevi S. J.

JOURNAL OF CHEMISTRY, 2013 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1155/2013/159125
  • Dergi Adı: JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Atatürk Üniversitesi Adresli: Evet

Özet

A new Pb(II) complex, [Pb(bp)(2)(btfa)(2)] 1, has been synthesized with bathophenanthroline (bp) and benzoyltrifluoroacetone (Hbtfa) and characterized by elemental analysis IR and H-1 NMR spectroscopy as well as by thermal properties and X-ray crystallography. The coordination number of the Pb(II) ions in 1 is eight, with the PbN4O4 coordination polyhedron containing a stereochemically inactive electron lone pair with holodirected coordination spheres. In solid state, there are pi...pi, CH...F, CH...O, and F...F interactions between adjacent units to generate 3D supramolecular structure.