Moisture adsorption isotherms and thermodynamics properties of sucuk (Turkish dry-fermented sausage)


Polatoğlu B., Beşe A. V., Kaya M., Aktas N.

Food and Bioproducts Processing, cilt.89, sa.4, ss.449-456, 2011 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 89 Sayı: 4
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1016/j.fbp.2010.06.003
  • Dergi Adı: Food and Bioproducts Processing
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.449-456
  • Anahtar Kelimeler: Sucuk, Isotherm, Mathematical models, Thermodynamic, Enthalpy-entropy compensation, Integral enthalpy, ENTHALPY-ENTROPY COMPENSATION, WATER SORPTION ISOTHERMS, STARCH POWDERS, FOOD, POTATO
  • Atatürk Üniversitesi Adresli: Evet

Özet

Moisture adsorption isotherms of sucuk were determined using the isopiestic method at 10 °C, 20 °C and 30 °C and within the range of 0.2-0.9 water activity. The isotherms of sucuk exhibited Type II behavior according to BET classification. The adsorption data were analyzed using mathematical equations of Halsey, Caurie, Peleg, Smith, Oswin, Henderson, Modified-BET, GAB, Ferro-Fontan and Harkins-Jura. The best fit of experimental data was obtained with Peleg equation in the range of temperatures and water activities investigated. Thermodynamic properties such as differential enthalpy and entropy, enthalpy-entropy compensation, spreading pressure, net integral enthalpy and entropy were determined from moisture adsorption isotherm data of sucuk. The net isosteric heat of sorption and differential entropy decreased with increasing moisture contents in an exponential function. The spreading pressure increased with increasing water activity, and decreased with increasing temperature. The net integral enthalpy decreased with increased moisture content. The integral entropy increased with moisture content, but it was negative in value. The enthalpy-entropy compensation theory was applied to water adsorption of sucuk. © 2010 The Institution of Chemical Engineers.